dc.description.abstract | In this thesis the diffusion of salt through porous carbon is studied. In particular, we use the colloidal charge sensor setup [1, 2] to determine the diffusion rate of salt through an externally charged porous carbon membrane. We succeeded in performing these measurements, but we had to use a few workarounds for practical problems. Salt transport across the membrane appeared to occur mainly via wide pores in which ions are hardly affected by changes in surface charge.
[1] Albert P. Philipse, Bonny W. M. Kuipers, and Agienus Vrij. "A thermodynamic gauge for mobile counter-ions from colloids and nanoparticles". In: Faraday Discuss. 181 (2015), pp. 103-121. doi: 10.1039/C4FD00261J. url: http://dx.doi.org/10.1039/C4FD00261J.
[2] Jos van Rijssel et al. "Thermodynamic Charge-to-Mass Sensor for Colloids, Proteins, and Polyelectrolytes". In: ACS Sensors 1.11 (2016), pp. 1344-1350. doi:
10.1021/acssensors.6b00510. url: http://dx.doi.org/10.1021/acssensors.6b00510. | |